Kapasitas Pengikatan Iodida dan Iod pada Karbon Aktif Konvensional dan Terbrominasi

  • Sunarhadijoso Soenarjo Pusat Radioisotop dan Radiofarmaka BATAN
  • Swasono R. Tamat Pusat Radioisotop dan Radiofarmaka BATAN
  • Ade Saputra Universitas Pancasila

Abstract

Related to the activities in a radioisotope processing laboratory at CDRR, BATAN, active carbon has a great potency and a role as adsorber for radioisotope immobilizing agent in process and installation systems. KAKEN Corporation, a CDRR's collaboration partner in Japan, has introduced a new type of active carbon namely KAKEN Brominated Active Carbon (KBAC) which is claimed to have an anionic exchange character. The presented experiment was thus performed to determine the iodide and iodine binding capacities of the KBAC resin as well as comparing to those of the conventional active carbon, which was also provided by KAKEN (KCAC). The experiment had been done using solutions of natural iodide and iodide - iodine mixtures. The binding capacities were determined by iodometry and iodatometry. In general the results obtained showed that the iodide-binding capacity of KBAC was higher than that of KCAC, but that the iodine-binding capacity of KCAC was higher. The KBAC showed that the binding capacity of iodide from iodide solutions was smaller than that from iodide-iodine samples, while the KCAC showed the reverse.

References

1. Manual for reactor produced radioisotopes. IAEA TECDOC-1340. Vienna: IAEA; 2003.p. 1–21.

2. Wangchang L, Yuying H, Yianwei W, et al. Research on removal of radioiodine by charcoal. Proceedings of Sino-French Seminar on L/ILW Management and Final Disposal, China National Nuclear Corp. Beijing; April 1993.p.82–89.

3. Freeman WP. Radioiodine testing of used nuclear grade activated carbon. Penetration Results from Samples Tested with and without Moisture Equilibration According to a Draft Revision of ASTM D 3803. CONF. 880815.1989;(2): 997-1002.

4. Soenarjo S, Gunawan AH, Wisnukaton K, et al. Pemisahan fraksi radioiod dalam proses 9Mo hasil fisi 235U dan penggunaannya untuk pembuatan Hippuran-1311. J Radioisotop dan Radiofarmaka. 1998. 1(1): 21 – 35.

5. Soenarjo S, Gunawan AH, Purwadi B, et al. Analysis of radioiodine fraction separated from production process of fission "Mo. Atom Indonesia. 1999.25(2): 101-11.

6. Kachef I, Cahill J, Huynh VT, Wolfshagen P. Nuclear mechano electronic installation, conceptual design description : building C. Dokumen Internal. BATAN AECL; 1986.

7. Hanamoto Y, Tatenuma K. High performance iodine adsorbent with high selectivity and removal efficiency. KAKEN Tech-News, No. 94. KBAC Leaflet. KAKEN Corp; 1999.

8. Vogel AI. A textbook of quantitative inorganic analysis including instrumental analysis. London: Longmans; 1961.

9. Departemen Kesehatan RI. Farmakope Indonesia. Edisi IV. Jakarta: Departemen Kesehatan Republik Indonesia; 1994.

10. Soenarjo S, Tamat ST, Suparman I, et al. RSG-GAS based radioisotopes and sharing program for regional back up supply. Regional Workshop in Production and Supply of Radioisotopes, IAEA-RAS 04/022, BATAN, Serpong 6-10 Oktober, 2003.

11. Gunawan AH, Soenarjo S. Uji kualitas sediaan hippuran-(1311) di pusat produksi radioisotop BATAN. Indo Kimia. 1996;2(3):76–87.

12. Soenarjo S dan Tamat SR. Current status of production and research of radioisotopes and radiopharmaceuticals in Indonesia. Proceeding of Workshop on the Utilization of Research Reactors, JAERI, Mito-City, Japan 28 November - 02 Desember, 1999: 450-459.
Published
2015-09-25
How to Cite
SOENARJO, Sunarhadijoso; TAMAT, Swasono R.; SAPUTRA, Ade. Kapasitas Pengikatan Iodida dan Iod pada Karbon Aktif Konvensional dan Terbrominasi. JURNAL ILMU KEFARMASIAN INDONESIA, [S.l.], v. 3, n. 2, p. 50-55, sep. 2015. ISSN 2614-6495. Available at: <http://jifi.farmasi.univpancasila.ac.id/index.php/jifi/article/view/606>. Date accessed: 16 apr. 2024.
Section
Articles